Journal article
The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene?
- Abstract:
- Reaction of K(3)P(7), FeCl(2), [NH(4)][B(C(6)H(5))(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP(7))(2)](2-). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted.
- Publication status:
- Published
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- Publisher copy:
- 10.1039/c1cc10236b
Authors
- Journal:
- Chemical Communications More from this journal
- Volume:
- 47
- Issue:
- 14
- Pages:
- 4111-4113
- Publication date:
- 2011-04-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- Language:
-
English
- Pubs id:
-
pubs:124328
- UUID:
-
uuid:f496eaa2-d129-4c3d-8106-e454ec965280
- Local pid:
-
pubs:124328
- Source identifiers:
-
124328
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 2011
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