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The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene?

Abstract:
Reaction of K(3)P(7), FeCl(2), [NH(4)][B(C(6)H(5))(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP(7))(2)](2-). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted.
Publication status:
Published

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Publisher copy:
10.1039/c1cc10236b

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Chemical communications (Cambridge, England)
Volume:
47
Issue:
14
Pages:
4111-4113
Publication date:
2011-04-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:f496eaa2-d129-4c3d-8106-e454ec965280
Source identifiers:
124328
Local pid:
pubs:124328
Language:
English

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