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The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene?

Abstract:
Reaction of K(3)P(7), FeCl(2), [NH(4)][B(C(6)H(5))(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP(7))(2)](2-). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted.
Publication status:
Published

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Publisher copy:
10.1039/c1cc10236b

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemical Communications
Volume:
47
Issue:
14
Pages:
4111-4113
Publication date:
2011-04-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
124328
Language:
English
Pubs id:
pubs:124328
UUID:
uuid:f496eaa2-d129-4c3d-8106-e454ec965280
Local pid:
pubs:124328
Deposit date:
2012-12-19

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