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Shallow donor state of hydrogen in In2O3 and SnO2: Implications for conductivity in transparent conducting oxides

Abstract:
Muonium, and by analogy hydrogen, is shown to form a shallow-donor state in In2 O3 and SnO2. The paramagnetic charge state is stable below ∼50 K in In2 O3 and ∼30 K in SnO2 which, coupled with its extremely small effective hyperfine splitting in both cases, allows its identification as the shallow-donor state. This has important implications for the controversial issue of the origins of conductivity in transparent conducting oxides. © 2009 The American Physical Society.
Publication status:
Published

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Publisher copy:
10.1103/PhysRevB.80.081201

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Journal:
PHYSICAL REVIEW B
Volume:
80
Issue:
8
Publication date:
2009-08-05
DOI:
EISSN:
1550-235X
ISSN:
1098-0121
URN:
uuid:f47df605-c4dc-48e8-82c5-6464452ff22d
Source identifiers:
41328
Local pid:
pubs:41328

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