- Abstract:
-
A feasibility study into the novel concept of using molecular oxygen to carry out one-step catalytic oxidation of cyclohexane to adipic acid in supercritical carbon dioxide over two types of catalysts, namely Co 2+/Mn2+/NaBr and Ag polyoxometallate, the silver decamolybdodivanadophosphate (Ag5PMo10V2O 40) was carried out. Poor activity and selectivity towards adipic acid were initially noted over the aqueous micellar Co2+/Mn 2+/NaBr catalyst for the cyclohexane oxidation in supercritical carb...
Expand abstract - Publisher copy:
- 10.1007/s10562-007-9015-y
-
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- Journal:
- Catalysis Letters
- Volume:
- 113
- Issue:
- 3-4
- Pages:
- 115-119
- Publication date:
- 2007-02-05
- DOI:
- EISSN:
-
1572-879X
- ISSN:
-
1011-372X
- URN:
-
uuid:f45aa16e-1a74-476a-b8d3-853f8d7ef723
- Source identifiers:
-
180286
- Local pid:
- pubs:180286
- Language:
- English
- Keywords:
- Copyright date:
- 2007
Journal article
Selective oxidation of cyclohexane in supercritical carbon dioxide
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