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Selective oxidation of cyclohexane in supercritical carbon dioxide

Abstract:

A feasibility study into the novel concept of using molecular oxygen to carry out one-step catalytic oxidation of cyclohexane to adipic acid in supercritical carbon dioxide over two types of catalysts, namely Co 2+/Mn2+/NaBr and Ag polyoxometallate, the silver decamolybdodivanadophosphate (Ag5PMo10V2O 40) was carried out. Poor activity and selectivity towards adipic acid were initially noted over the aqueous micellar Co2+/Mn 2+/NaBr catalyst for the cyclohexane oxidation in supercritical carb...

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Publisher copy:
10.1007/s10562-007-9015-y

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Journal:
Catalysis Letters
Volume:
113
Issue:
3-4
Pages:
115-119
Publication date:
2007-02-05
DOI:
EISSN:
1572-879X
ISSN:
1011-372X
URN:
uuid:f45aa16e-1a74-476a-b8d3-853f8d7ef723
Source identifiers:
180286
Local pid:
pubs:180286

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