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Mechanical properties of colloidal crystals at fluid interfaces

Abstract:
We characterise the local mechanical properties of two-dimensional colloidal crystals with hexagonal symmetry assembled at the flat interface between oil and water. Our experiments elucidate the conditions under which the material behaves isotropically, as opposed to those where the microstructure plays a major role. Brownian fluctuations are used to extract the stiffness of the lattice under the continuum approximation, whereas at larger displacements, obtained by optically driving one particle through the structure, the mechanical resistance of the lattice depends on both the area fraction and the direction of the applied force. Remarkably, the minimum resistance does not necessarily correspond to a probe being driven between neighbours, i.e. at 30° with respect to the crystal axes.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1088/2515-7639/abd019

Authors


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Role:
Author
ORCID:
0000-0002-0067-0712
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Institution:
University of Oxford
Department:
CHEMISTRY
Sub department:
Physical & Theoretical Chem
Role:
Author
ORCID:
0000-0003-1751-0958


Publisher:
IOP Publishing
Journal:
Journal of Physics: Materials More from this journal
Volume:
4
Issue:
2
Article number:
025001
Publication date:
2021-01-12
Acceptance date:
2020-12-02
DOI:
EISSN:
2515-7639


Language:
English
Keywords:
Pubs id:
1163516
Local pid:
pubs:1163516
Deposit date:
2021-02-25

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