Journal article
Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H<sub>2</sub>and D<sub>2</sub>
- Abstract:
- We describe the synthesis of the coordinatively unsaturated Zintl clusters [Rh(L){η3-Ge9(Hyp)3}] (where L = PMe3, PPh3, IMe4 or [W(Cp)2H2]). These species are active catalysts in H/D exchange and C–H bond activation reactions.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Version of record, pdf, 838.7KB, Terms of use)
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- Publisher copy:
- 10.1039/d2sc02552c
Authors
+ Engineering and Physical Sciences Research Council
More from this funder
- Funder identifier:
- 10.13039/501100000266
- Grant:
- EP/M024210
- Publisher:
- Royal Society of Chemistry
- Journal:
- Chemical Science More from this journal
- Volume:
- 13
- Issue:
- 25
- Pages:
- 7626-7633
- Publication date:
- 2022-06-29
- DOI:
- EISSN:
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2041-6539
- ISSN:
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2041-6520
- Language:
-
English
- Keywords:
- Pubs id:
-
1264940
- Local pid:
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pubs:1264940
- Source identifiers:
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W4285258351
- Deposit date:
-
2026-04-24
- ARK identifier:
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Terms of use
- Copyright date:
- 2022
- Licence:
- CC Attribution (CC BY)
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