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Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.

Abstract:
A rhodium(I) catalyst incorporating the Me-DuPhos ligand promotes enantioselective intermolecular hydroacylation between beta-S-aldehydes and 1,3-disubstituted allenes. The nonconjugated enone products are obtained in good yields and with high enantioselectivities.
Publication status:
Published

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Publisher copy:
10.1021/ja8069133
Journal:
Journal of the American Chemical Society More from this journal
Volume:
130
Issue:
51
Pages:
17232-17233
Publication date:
2008-12-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Keywords:
Pubs id:
pubs:52478
UUID:
uuid:f363cfbf-dc83-4aa6-b5e7-720e60d8c343
Local pid:
pubs:52478
Source identifiers:
52478
Deposit date:
2012-12-19

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