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{Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental Approach

Abstract:

We report the synthesis, structural characterisation andsolution-phase dynamics of a series of polyaromatic hydrocarbon complexes of the 12-electron {Rh(PiBu 3) 2} + fragment. Crystal structures of this fragment with benzene, naphthalene, anthracene, pyrene, triphenylene and coronene are described, alongside their solution NMR spectroscopic data. The ligands map out a systematic increase in size of the aromatic subunit, a...

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Publication status:
Published

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Publisher copy:
10.1002/ejic.201001263

Authors


Chaplin, AB More by this author
McGrady, JE More by this author
Alibadi, MAM More by this author
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Journal:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume:
2011
Issue:
10
Pages:
1614-1625
Publication date:
2011-04-05
DOI:
EISSN:
1099-0682
ISSN:
1434-1948
URN:
uuid:f35ac2c9-f6c4-43c6-b5df-429154abda2f
Source identifiers:
132516
Local pid:
pubs:132516

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