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THE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTION

Abstract:
It is shown using linear sweep and rotating-disc voltammetry that the reduction of the dye fluorescein at ca. pH 6 in aqueous solution proceeds via a DISP2 mechanism. In particular the rotating-disc measurements show voltammetric waves which display a shift in the half-wave potential with disc rotation speed and which also analyse to give curved Tafel plots entirely in agreement with the behaviour predicted theoretically for a DISP2 process on the basis of a reaction layer treatment.
Publication status:
Published

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Publisher copy:
10.1039/f19888400483

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I More from this journal
Volume:
84
Issue:
2
Pages:
483-489
Publication date:
1988-01-01
DOI:
ISSN:
0300-9599


Language:
English
Pubs id:
pubs:42937
UUID:
uuid:f32d263e-792e-4bb9-93df-ac79acc6cda9
Local pid:
pubs:42937
Source identifiers:
42937
Deposit date:
2012-12-19

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