Journal article

Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides

Abstract:: Dihydrogen loss from the 14-electron Rh(III) bis-phosphine dihydride [Rh(PiBu3)2H2][BArF4] forms a complex tentatively identified as [Rh(PiBu 3)2(L2)][BArF4] (L 2 = solvent or agostic interactions), which reacts with dichloro ethane or fluorobenzene to form [Rh(PiBu3) 2(ClCH2CH2Cl)][BArF4] and [Rh(PiBu3)2(η6-C 6H5F)][BArF4], respectively. [Rh(PiBu3)2(L)2[-[BAr F4] or its adducts undergo oxidative addition of aryl halides (C6H5X; X = Cl, Br) at room temperature to give the dimeric species [Rh(PiBu3)2(C 6H5)(μ-X)]2. © 2008 American Chemical Society.

Publication status:: Published

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APA Style

Douglas, T., Chaplin, A. B., & Weller, A. (2008). Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides. ORGANOMETALLICS, 27(13), 2918–2921.

MLA Style

Douglas, T, et al. “Dihydrogen Loss from a 14-Electron Rhodium(III) Bis-Phosphine Dihydride to Give a Rhodium(I) Complex That Undergoes Oxidative Addition with Aryl Chlorides.” ORGANOMETALLICS, vol. 27, no. 13, 2008, pp. 2918–21.

Chicago Style

Douglas, T, AB Chaplin, and A Weller. 2008. “Dihydrogen Loss from a 14-Electron Rhodium(III) Bis-Phosphine Dihydride to Give a Rhodium(I) Complex That Undergoes Oxidative Addition with Aryl Chlorides.” ORGANOMETALLICS 27 (13): 2918–21.
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Publisher copy:: 10.1021/om800373d

Authors

+ Douglas, T More by this author

Role:: Author

+ Chaplin, AB More by this author

Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: ORGANOMETALLICS More from this journal
Volume:: 27
Issue:: 13
Pages:: 2918-2921
Publication date:: 2008-07-14
DOI:: 10.1021/om800373d
EISSN:: 1520-6041
ISSN:: 0276-7333

Language:: English
Pubs id:: pubs:40823
UUID:: uuid:f3036882-8aa3-4c67-a260-c95dc3d39318
Local pid:: pubs:40823
Source identifiers:: 40823
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_f30368828aa34c67a260c95dc3d39318

Terms of use

Copyright date:: 2008

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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