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Thesis

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions

Abstract:

Chapter 1 is an overview of the key developments in rhodium-catalysed hydroacylation. The main focus of this chapter is the use of various chelation strategies for the stabilisation of key rhodium-acyl intermediates. In addition, the more recent emergence of regioselective hydroacylation processes has been highlighted.

Chapter 2 discloses the branched-selective intermolecular hydroacylation of 1,3-dienes and S-chelating aldehydes to afford synthetically useful 1,5-dione products. T...

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Institution:
University of Oxford
Research group:
Professor Michael Willis
Oxford college:
Linacre College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory

Contributors

Role:
Supervisor
Publication date:
2012
Type of award:
DPhil
Level of award:
Doctoral
URN:
uuid:f2993627-6550-42a5-b6e1-9d63f8268dbb
Local pid:
ora:7316

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