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The kinetics of ferrocene volatilisation from an ionic liquid.

Abstract:

The volatilisation of ferrocene (Fc), dissolved in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C(4)mpyrr][NTf(2)], to the gas phase has been indirectly monitored by cyclic voltammetry and chronoamperometry. Simulation of the observed trends in concentration with time using a simple model allowed quantification of the process. Volatilisation of dissolved Fc under flowing wet and dry dinitrogen gas (N(2)) was found to be kinetically limited with a rate con...

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Publication status:
Published

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Publisher copy:
10.1002/cphc.201100204

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Chemphyschem : a European journal of chemical physics and physical chemistry More from this journal
Volume:
12
Issue:
9
Pages:
1708-1713
Publication date:
2011-06-01
DOI:
EISSN:
1439-7641
ISSN:
1439-4235
Language:
English
Keywords:
Pubs id:
pubs:141339
UUID:
uuid:f28d731f-3977-4ddd-8d0f-ec95100c99e0
Local pid:
pubs:141339
Source identifiers:
141339
Deposit date:
2012-12-19

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