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Structural and magnetic properties of Pr18Li8Fe5-xMxO39 (M = Ru, Mn, Co)

Abstract:

A polycrystalline sample of Pr18Li8Fe4RuO39 has been synthesized by a solid state method and characterized by neutron powder diffraction, magnetometry and Mössbauer spectroscopy; samples of Pr18Li8Fe5-xMnxO 39 and Pr18Li8Fe5-xCoxO 39 (x=1, 2) have been studied by magnetometry. All these compounds adopt a cubic structure (space group Pm over(3, -) n, a0∼11.97 Å) based on intersecting 〈111〉 chains made up of alternating octahedral and trigonal-prismatic coordination sites. These chains occupy c...

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Publication status:
Published

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Publisher copy:
10.1016/j.jssc.2009.04.002

Authors


Dutton, SE More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Grandjean, F More by this author
Sougrati, MT More by this author
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Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
182
Issue:
7
Pages:
1638-1648
Publication date:
2009-07-05
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
URN:
uuid:f2755d93-b93f-4729-8084-688022042204
Source identifiers:
41296
Local pid:
pubs:41296

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