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Giving physical insight into the Butler-Volmer model of electrode kinetics: Application of asymmetric Marcus-Hush theory to the study of the electroreductions of 2-methyl-2-nitropropane, cyclooctatetraene and europium(III) on mercury microelectrodes

Abstract:

The asymmetric Marcus-Hush (MH) model for electrode kinetics is applied to the kinetic study of the electroreduction of 2-methyl-2-nitropropane in acetonitrile, cyclooctatetraene in dimethylsulfoxide and europium(III) in aqueous solution, using mercury microhemispheres as working electrodes. This kinetic model includes the possibility of the oxidative and reductive processes having different reorganization energies due to differences between the force constants of the electroactive species. F...

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Publication status:
Published

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Authors


Henstridge, MC More by this author
Laborda, E More by this author
Suwatchara, D More by this author
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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
672
Pages:
45-52
Publication date:
2012-05-01
DOI:
ISSN:
1572-6657
URN:
uuid:f271f1cf-752a-4bda-b441-75953e19b4a1
Source identifiers:
325344
Local pid:
pubs:325344

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