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The stereodivergent aziridination of allylic carbamates, amides and sulfonamides

Abstract:
A stereodivergent protocol for the aziridination of a range of cyclic allylic amine derivatives has been developed. syn-Products can be obtained in >99:1 dr under H-bonded control and anti-products are obtained in >99:1 dr under steric control by judicious choice of the N-protecting groups. © 2010 Elsevier Ltd. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1016/j.tet.2010.06.059

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Journal:
TETRAHEDRON More from this journal
Volume:
66
Issue:
34
Pages:
6806-6813
Publication date:
2010-08-21
DOI:
ISSN:
0040-4020


Language:
English
Keywords:
Pubs id:
pubs:71200
UUID:
uuid:f2548e2e-90be-4996-9c94-c8dc64142970
Local pid:
pubs:71200
Source identifiers:
71200
Deposit date:
2012-12-19
ARK identifier:

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