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Variable dimensionality in the UO2(CH3CO2)(2)center dot 2H(2)O/HF/isonicotinic acid system: Synthesis and structures of zero-, one-, and two-dimensional uranium isonicotinates

Abstract:

Four new uranium isonicotinate framework solids were synthesized in the UO2(CH3CO2)· 2H2O/HF/isonicotinic acid system under hydrothermal conditions. The isolated uranium isonicotinates span a range of dimensionalities from zero-dimensional UO2(C5H5NCO2)(CH3 CO2)2 (1), one-dimensional [UO2F2] [C5H5NCO2] (2) and [UO2F3][C5H6NCO2] ·0.5H2O (3), and two-dimensional [UO2F2]2[C5H5 NCO2]·H2O (4). Regions of phase stability were determined using composition space diagrams, which were used to demonstra...

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Publication status:
Published

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Publisher copy:
10.1021/cm021722n

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
CHEMISTRY OF MATERIALS More from this journal
Volume:
15
Issue:
10
Pages:
1970-1975
Publication date:
2003-05-20
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
Language:
English
Pubs id:
pubs:51205
UUID:
uuid:f214fd5e-4cb8-4489-87c4-2ded15dcab57
Local pid:
pubs:51205
Source identifiers:
51205
Deposit date:
2012-12-19

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