Journal article

Metal-catalyzed syntheses of abridged CDE rings of rubriflordilactones A and B.

Abstract:: The development of complementary palladium- and cobalt-catalyzed approaches to tricyclic arylsilanes suitable for elaboration into the CDE ring systems of rubriflordilactones A and B is reported. Microwave conditions are required to effect a cobalt-catalyzed triyne cyclotrimerization, which critically depends on the substitution pattern of the triyne termini. Mild conditions to elaborate these arylsilanes to the CDE cores of the natural products are described.

Publication status:: Published

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Cite

Cite this record

APA Style

Goh, S., Baars, H., Gockel, B., & Anderson, E. (2012). Metal-catalyzed syntheses of abridged CDE rings of rubriflordilactones A and B. Organic Letters, 14(24), 6278–6281.

MLA Style

Goh, S., et al. “Metal-Catalyzed Syntheses of Abridged CDE Rings of Rubriflordilactones A and B.” Organic Letters, vol. 14, no. 24, 2012, pp. 6278–81.

Chicago Style

Goh, S, H Baars, B Gockel, and E Anderson. 2012. “Metal-Catalyzed Syntheses of Abridged CDE Rings of Rubriflordilactones A and B.” Organic Letters 14 (24): 6278–81.
Share
Print

Access Document

Publisher copy:: 10.1021/ol303041j

Authors

+ Goh, S More by this author

Role:: Author

+ Baars, H More by this author

Role:: Author

+ Gockel, B More by this author

Role:: Author

+ Anderson, E More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

Journal:: Organic letters More from this journal
Volume:: 14
Issue:: 24
Pages:: 6278-6281
Publication date:: 2012-12-01
DOI:: 10.1021/ol303041j
EISSN:: 1523-7052
ISSN:: 1523-7060

Language:: English
Keywords:: Stereoisomerism

Palladium

Triterpenes

Molecular Structure

Schisandra

Catalysis
Pubs id:: pubs:365522
UUID:: uuid:f18c0f39-fb7f-4c0e-b317-f571bb289ee9
Local pid:: pubs:365522
Source identifiers:: 365522
Deposit date:: 2013-11-16

Terms of use

Copyright date:: 2012

Licence:: Terms and Conditions of Use for Oxford University Research Archive

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP