Journal article icon

Journal article

The interaction of gold(I) cations with 1,3-dienes.

Abstract:
Slip-sliding away: Gold(I) cations bind to only one double bond of a 1,3-diene unit but can glide over the C 4 backbone on a low-activation-energy pathway. However, the binding mode is influenced by substituents on the diene backbone, which also induces a significantly higher barrier to migration. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1002/anie.201102750

Authors



Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
50
Issue:
33
Pages:
7592-7595
Publication date:
2011-08-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:175469
UUID:
uuid:f1344c41-2e35-4a85-8429-6080a0c794f8
Local pid:
pubs:175469
Source identifiers:
175469
Deposit date:
2012-12-19

Terms of use



Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP