Journal article
The interaction of gold(I) cations with 1,3-dienes.
- Abstract:
- Slip-sliding away: Gold(I) cations bind to only one double bond of a 1,3-diene unit but can glide over the C 4 backbone on a low-activation-energy pathway. However, the binding mode is influenced by substituents on the diene backbone, which also induces a significantly higher barrier to migration. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
- Publication status:
- Published
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Authors
- Journal:
- Angewandte Chemie (International ed. in English) More from this journal
- Volume:
- 50
- Issue:
- 33
- Pages:
- 7592-7595
- Publication date:
- 2011-08-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:175469
- UUID:
-
uuid:f1344c41-2e35-4a85-8429-6080a0c794f8
- Local pid:
-
pubs:175469
- Source identifiers:
-
175469
- Deposit date:
-
2012-12-19
Terms of use
- Copyright date:
- 2011
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