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NEW BIS(FERROCENECARBONYL)- AND BIS(FERROCENYL)-APPENDED DIAZATETRATHIA MIXED-DONOR MACROCYCLIC LIGANDS AND THEIR COPPER-(II) AND COPPER-(I) COMPLEXES

Abstract:

New bis(ferrocenecarbonyl)-, bis(ferrocenyl)- and dibenzyl-appended diazatetrathia mixed-donor macrocyclic ligands L1, L2 and L3 have been prepared. Copper-(II) and -(I) complexes of these ligands have been isolated and characterised. Single-crystal X-ray structures of 7,16-bis(ferrocenemethyl)-1,4,10,13-tetrathia-7,16-diazacyclooctadecane (L2) and of its copper(I) complex [CuL2]PF6 have also been determined. Electrochemical investigations reveal the respective ferrocene-ferrocenium redox cou...

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Publication status:
Published

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Publisher copy:
10.1039/dt9910002485

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
10
Pages:
2485-2492
Publication date:
1991-10-05
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:f0e4c464-2267-4bad-84e4-bea465252616
Source identifiers:
46141
Local pid:
pubs:46141
Language:
English

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