- Abstract:
-
New bis(ferrocenecarbonyl)-, bis(ferrocenyl)- and dibenzyl-appended diazatetrathia mixed-donor macrocyclic ligands L1, L2 and L3 have been prepared. Copper-(II) and -(I) complexes of these ligands have been isolated and characterised. Single-crystal X-ray structures of 7,16-bis(ferrocenemethyl)-1,4,10,13-tetrathia-7,16-diazacyclooctadecane (L2) and of its copper(I) complex [CuL2]PF6 have also been determined. Electrochemical investigations reveal the respective ferrocene-ferrocenium redox cou...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/dt9910002485
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
- Issue:
- 10
- Pages:
- 2485-2492
- Publication date:
- 1991-10-05
- DOI:
- EISSN:
-
1364-5447
- ISSN:
-
0300-9246
- URN:
-
uuid:f0e4c464-2267-4bad-84e4-bea465252616
- Source identifiers:
-
46141
- Local pid:
- pubs:46141
- Language:
- English
- Copyright date:
- 1991
Journal article
NEW BIS(FERROCENECARBONYL)- AND BIS(FERROCENYL)-APPENDED DIAZATETRATHIA MIXED-DONOR MACROCYCLIC LIGANDS AND THEIR COPPER-(II) AND COPPER-(I) COMPLEXES
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