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Structural studies on the hydration of L-glutamic acid in solution.

Abstract:

A combination of neutron diffraction augmented with isotopic substitution and computer modeling using empirical potential structure refinement has been used to extract detailed structural information for L-glutamic acid dissolved in 2 M NaOH solution. This work shows that the tetrahedral hydrogen bonding network in water is severely disrupted by the addition of glutamic acid and NaOH, with the number of water-water hydrogen bonds being reduced from 1.8 bonds per water molecule in pure water t...

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Publication status:
Published

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Publisher copy:
10.1021/jp062383e

Authors


McLain, SE More by this author
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Institution:
University of Oxford
Department:
Oxford, MSD, Biochemistry
Journal:
The journal of physical chemistry. B
Volume:
110
Issue:
42
Pages:
21251-21258
Publication date:
2006-10-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:f0c7a794-2f33-43d6-a4c4-08313ff9aa65
Source identifiers:
100581
Local pid:
pubs:100581

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