Journal article

Intramolecular cyclopropanation of epichlorohydrin-derived unsaturated chlorohydrins

Abstract:: Concise stereoselective syntheses of bicyclo[3.1.0]hexan-2-ols and a bicyclo[4.1.0]heptan-2-ol are achieved via regioselective ring-opening of epichlorohydrin with allylic and homoallylic Grignard reagents, followed by lithium 2,2,6,6-tetramethylpiperidide-induced intramolecular cyclopropanation of the resulting unsaturated chlorohydrins. © Georg Thieme Verlag Stuttgart.

Publication status:: Published

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APA Style

Hodgson, D., Chung, Y., & Paris, J. (2005). Intramolecular cyclopropanation of epichlorohydrin-derived unsaturated chlorohydrins. SYNTHESIS-STUTTGART, 13, 2264–2266.

MLA Style

Hodgson, D, et al. “Intramolecular Cyclopropanation of Epichlorohydrin-Derived Unsaturated Chlorohydrins.” SYNTHESIS-STUTTGART, no. 13, 2005, pp. 2264–66.

Chicago Style

Hodgson, D, Y Chung, and J Paris. 2005. “Intramolecular Cyclopropanation of Epichlorohydrin-Derived Unsaturated Chlorohydrins.” SYNTHESIS-STUTTGART, no. 13: 2264–66.
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Publisher copy:: 10.1055/s-2005-869973

Authors

+ Hodgson, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Chung, Y More by this author

Role:: Author

+ Paris, J More by this author

Role:: Author

Journal:: SYNTHESIS-STUTTGART More from this journal
Issue:: 13
Pages:: 2264-2266
Publication date:: 2005-08-19
DOI:: 10.1055/s-2005-869973
EISSN:: 1437-210X
ISSN:: 0039-7881

Language:: English
Keywords:: lithium 2,2,6,6-tetramethylpiperidide

epichlorohydrin

Grignard reagents

unsaturated chlorohydrin

intramolecular cyclopropanation
Pubs id:: pubs:39569
UUID:: uuid:f080853f-de9b-44a7-bf03-fb87996ea3e2
Local pid:: pubs:39569
Source identifiers:: 39569
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_f080853fde9b44a7bf03fb87996ea3e2

Terms of use

Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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