Journal article

The 2-phosphaethynolate anion: a convenient synthesis and [2+2] cycloaddition chemistry.

Abstract:: Hip to be square: Direct carbonylation of solutions of the heptaphosphide trianion (P7(3-)) afforded the phosphaethynolate anion in moderate yields. This species undergoes [2+2] cycloaddition reactions with diphenylketene and bis(2,6-diisopropylphenyl)carbodiimide to yield the anionic four-membered heterocycles P[C(O)]2C(C6H5)2(-) and PC(O)(CNDipp)NDipp(-) .

Publication status:: Published

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APA Style

Jupp, A., & Goicoechea, J. (2013). The 2-phosphaethynolate anion: a convenient synthesis and [2+2] cycloaddition chemistry. Angewandte Chemie (International Ed. in English), 52(38), 10064–10067.

MLA Style

Jupp, A, and J Goicoechea. “The 2-Phosphaethynolate Anion: a Convenient Synthesis and [2+2] Cycloaddition Chemistry.” Angewandte Chemie (International Ed. in English), vol. 52, no. 38, 2013, pp. 10064–67.

Chicago Style

Jupp, A, and J Goicoechea. 2013. “The 2-Phosphaethynolate Anion: a Convenient Synthesis and [2+2] Cycloaddition Chemistry.” Angewandte Chemie (International Ed. in English) 52 (38): 10064–67.
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Publisher copy:: 10.1002/anie.201305235

Authors

+ Jupp, A More by this author

Role:: Author

+ Goicoechea, J More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 52
Issue:: 38
Pages:: 10064-10067
Publication date:: 2013-09-01
DOI:: 10.1002/anie.201305235
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: cycloaddition

phosphaethynolate anion

polyphosphides

organophosphorus chemistry

phosphorus
Pubs id:: pubs:416556
UUID:: uuid:f0517cf2-255a-4458-81aa-30aa3c6559f6
Local pid:: pubs:416556
Source identifiers:: 416556
Deposit date:: 2013-11-16
ARK identifier:: ark:/29072/ora_f0517cf2255a445881aa30aa3c6559f6

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Copyright date:: 2013

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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