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Anion Recognition by Highly Sterically Encumbered 1,2-Diborylferrocenes

Abstract:
The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes2)2 is found to be highly selective for CN-, with the uptake of F- being shown to be not only thermodynamically less favorable but also kinetically much slower. © 2010 American Chemical Society.
Publication status:
Published

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Publisher copy:
10.1021/om1005337

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
ORGANOMETALLICS
Volume:
29
Issue:
21
Pages:
4762-4765
Publication date:
2010-11-08
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:f032c5b7-77b3-4575-bbe8-b28c2f89d982
Source identifiers:
103674
Local pid:
pubs:103674
Language:
English

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