Journal article
Anion Recognition by Highly Sterically Encumbered 1,2-Diborylferrocenes
- Abstract:
- The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes2)2 is found to be highly selective for CN-, with the uptake of F- being shown to be not only thermodynamically less favorable but also kinetically much slower. © 2010 American Chemical Society.
- Publication status:
- Published
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- Publisher copy:
- 10.1021/om1005337
Authors
- Journal:
- ORGANOMETALLICS More from this journal
- Volume:
- 29
- Issue:
- 21
- Pages:
- 4762-4765
- Publication date:
- 2010-11-08
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- Language:
-
English
- Pubs id:
-
pubs:103674
- UUID:
-
uuid:f032c5b7-77b3-4575-bbe8-b28c2f89d982
- Local pid:
-
pubs:103674
- Source identifiers:
-
103674
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 2010
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