Journal article

Rhodium-catalyzed reductive aldol reactions using aldehydes as the stoichiometric reductants.

Abstract:: Chelated acyl rhodium hydrides, generated from the addition of [Rh(dppe)]ClO4 to beta-sulfide-substituted aldehydes, can function as the stoichiometric reductants in reductive aldol processes. Unsaturated nitriles, esters, and ketones can be used as enolate equivalents, and a variety of simple alpha- and beta-substituted aldehydes can be employed. The use of a second, more electrophilic, aldehyde allows three-component reactions to be performed.

Publication status:: Published

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APA Style

Willis, M., & Woodward, R. (2005). Rhodium-catalyzed reductive aldol reactions using aldehydes as the stoichiometric reductants. Journal of the American Chemical Society, 127(51), 18012–18013.

MLA Style

Willis, M, and R Woodward. “Rhodium-Catalyzed Reductive Aldol Reactions Using Aldehydes as the Stoichiometric Reductants.” Journal of the American Chemical Society, vol. 127, no. 51, 2005, pp. 18012–13.

Chicago Style

Willis, M, and R Woodward. 2005. “Rhodium-Catalyzed Reductive Aldol Reactions Using Aldehydes as the Stoichiometric Reductants.” Journal of the American Chemical Society 127 (51): 18012–13.
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Publisher copy:: 10.1021/ja056130v

Authors

+ Willis, M More by this author

Role:: Author

+ Woodward, R More by this author

Role:: Author

Journal:: Journal of the American Chemical Society More from this journal
Volume:: 127
Issue:: 51
Pages:: 18012-18013
Publication date:: 2005-12-01
DOI:: 10.1021/ja056130v
EISSN:: 1520-5126
ISSN:: 0002-7863

Language:: English
Pubs id:: pubs:52467
UUID:: uuid:f0142f92-80c2-4102-bac4-0276516b68ea
Local pid:: pubs:52467
Source identifiers:: 52467
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_f0142f9280c24102bac40276516b68ea

Terms of use

Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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