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POLARIZATION EFFECTS ON THE STRUCTURE AND DYNAMICS OF IONIC MELTS

Abstract:
The effect of induced dipoles on the structure and dynamics of melts of stoichiometry MX 2 is discussed. Interest centres on the case of M being a small, highly polarizing cation and X a highly polarizable anion. It is shown that 'covalent' effects on the short range structure and the appearance of a pre-peak in the structure factor may be explained within a purely ionic model. A connection between these structural features and the dynamical properties of 'strong' liquids is suggested.
Publication status:
Published

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Publisher copy:
10.1088/0953-8984/6/23A/020

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Volume:
6
Issue:
23A
Pages:
A151-A155
Publication date:
1994-06-06
DOI:
EISSN:
1361-648X
ISSN:
0953-8984
URN:
uuid:eff1d3fc-c11b-40bd-b6a3-7d877d483a9c
Source identifiers:
60190
Local pid:
pubs:60190

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