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POLARIZATION EFFECTS ON THE STRUCTURE AND DYNAMICS OF IONIC MELTS

Abstract:
The effect of induced dipoles on the structure and dynamics of melts of stoichiometry MX 2 is discussed. Interest centres on the case of M being a small, highly polarizing cation and X a highly polarizable anion. It is shown that 'covalent' effects on the short range structure and the appearance of a pre-peak in the structure factor may be explained within a purely ionic model. A connection between these structural features and the dynamical properties of 'strong' liquids is suggested.
Publication status:
Published

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Publisher copy:
10.1088/0953-8984/6/23A/020

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Volume:
6
Issue:
23A
Pages:
A151-A155
Host title:
JOURNAL OF PHYSICS-CONDENSED MATTER
Publication date:
1994-06-06
DOI:
EISSN:
1361-648X
ISSN:
0953-8984
Source identifiers:
60190
Pubs id:
pubs:60190
UUID:
uuid:eff1d3fc-c11b-40bd-b6a3-7d877d483a9c
Local pid:
pubs:60190
Deposit date:
2012-12-19

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