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Equality of diffusion-limited chronoamperometric currents to equal area spherical and cubic nanoparticles on a supporting electrode surface

Abstract:
We computationally investigate the chronoamperometric current response of spherical and cubic particles on a supporting insulating surface. By using the method of finite di?erences and random walk simulations, we can show that both systems exhibit identical responses on all time scales if their exposed surface areas are equal. This result enables a simple and computationally effcient method to treat certain spherical geometries in random walk based noise investigations.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.cplett.2014.01.036

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Publisher:
Elsevier
Journal:
Chemical Physics Letters More from this journal
Volume:
595-596
Pages:
31-34
Publication date:
2014-02-06
DOI:
ISSN:
0009-2614


Keywords:
Pubs id:
pubs:448573
UUID:
uuid:efd868bc-8ef4-4743-8d9a-713e3614d125
Local pid:
pubs:448573
Source identifiers:
448573
Deposit date:
2014-06-17
ARK identifier:

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