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The structure of CO-OCS: A spectroscopic and theoretical investigation

Abstract:

The spectrum of the weakly bound complex CO-OCS has been measured in the infrared using direct absorption diode laser spectroscopy in a supersonic jet, and in the microwave region using a pulsed nozzle Fourier-transform instrument. In addition, microwave spectra of the two isotopomers 13CO-OCS and CO-OC34S were recorded. A T shaped structure has been determined with the carbon atom in CO closest to the OCS (RMS angle±20·5° with respect to the intermolecular axis) and the sulphur end of OCS po...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
MOLECULAR PHYSICS
Volume:
88
Issue:
4
Pages:
899-914
Publication date:
1996-07-05
ISSN:
0026-8976
URN:
uuid:efa65529-376b-4d2e-9ed3-5a692c23377f
Source identifiers:
45223
Local pid:
pubs:45223
Language:
English

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