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Reactions of nitric oxide on Rh6+ clusters: abundant chemistry and evidence of structural isomers.

Abstract:

We report the first results of a new instrument for the study of the reactions of naked metal cluster ions using techniques developed by Professor Bondybey to whom this issue is dedicated. Rh6+ ions have been produced using a laser vaporization source and injected into a 3 T Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer where they are exposed to a low pressure (< 10(-8) mbar) of nitric oxide, NO. This system exhibits abundant chemistry, the first stages of which we i...

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Publication status:
Published

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Publisher copy:
10.1039/b415414b

Authors


Anderson, ML More by this author
Barrow, MP More by this author
Woodruff, DP More by this author
Drewello, T More by this author
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Journal:
Physical chemistry chemical physics : PCCP
Volume:
7
Issue:
5
Pages:
975-980
Publication date:
2005-03-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:ef5af2bd-dd55-4cdc-b2f4-4b4e81f99fa9
Source identifiers:
58992
Local pid:
pubs:58992
Language:
English

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