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Unraveling the mechanism of cascade reactions of zincke aldehydes.

Abstract:
The thermal pericyclic cascade rearrangement of Zincke aldehydes (5-(dialkylamino)-2,4-pentadienals) to afford Z-α,β,γ,δ-unsaturated amides discovered by the Vanderwal group has been studied in depth using quantum mechanical methods. Two mechanist...Expand abstract...
Publication status:
Published

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Publisher copy:
10.1021/ja107988b

Authors


Steinhardt, SE More by this author
Vanderwal, CD More by this author
Journal:
Journal of the American Chemical Society More in this journal
Volume:
133
Issue:
11
Pages:
3895-3905
Publication date:
2011-03-19
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:ef4e745f-14d5-43bb-9778-ffc7660ae246
Source identifiers:
135022
Local pid:
pubs:135022

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