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Role of halides in selective oxidation reactions

Abstract:
The role of chlorine, in various chemical forms, in the methane activation reaction has been investigated. It has been found that although there is a release of methyl chloride and HCl from the surface of chloride-containing catalysts during the methane coupling reaction, very little ethene is produced from ethane in the post catalyst volume. However, depending on the experimental conditions used, it is possible to envisage an important contribution from gas phase reactions in the catalyst bed.

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Publisher copy:
10.1016/0920-5861(90)85045-P

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Journal:
Catalysis Today More from this journal
Volume:
6
Issue:
4
Pages:
503-510
Publication date:
1990-02-01
DOI:
ISSN:
0920-5861


Language:
English
Pubs id:
pubs:180199
UUID:
uuid:eebe35a9-381c-4b8f-88eb-3f24bde35cf7
Local pid:
pubs:180199
Source identifiers:
180199
Deposit date:
2013-02-20
ARK identifier:

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