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Surfactant-free emulsion electrosynthesis via power ultrasound: electrocatalytic formation of carbon-carbon bonds

Abstract:

Proof-of-concept of the mediated electrosynthesis of carbon-carbon bonds in totally 'green' surfactant-free emulsion media generated by application of power ultrasound to a biphasic water-organic mixture is illustrated by reference to three systems, some requiring further activation by light, and each catalysed by vitamin B12. The voltammetry of aqueous vitamin B12 solutions at an electrode modified with microdroplets of the organic reactant is employed to gain an insight into the electrocata...

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Publication status:
Published

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Publisher copy:
10.1039/b205706a

Authors


Davies, TJ More by this author
Nuthakki, B More by this author
Rusling, JF More by this author
France, RR More by this author
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Journal:
GREEN CHEMISTRY
Volume:
4
Issue:
6
Pages:
570-577
Publication date:
2002
DOI:
EISSN:
1463-9270
ISSN:
1463-9262
URN:
uuid:eeb6ba02-92c0-4de7-8a01-39ae58230408
Source identifiers:
38480
Local pid:
pubs:38480
Language:
English

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