Journal article

Synthesis of polyyne rotaxanes.

Abstract:: Active-metal templating has been used to synthesize rotaxanes consisting of a phenanthroline-based macrocycle threaded around a C8, C12, or C20 polyyne chain. The crystal structure of the C12 rotaxane has been determined. In the rhenium(I) carbonyl complex of this rotaxane, with Re(CO)(3)Cl coordinated to the phenanthroline macrocycle, the proximity of the polyyne chain quenches the luminescence of the rhenium. These rotaxanes offer a new approach to controlling the environment and interactions of a polyyne chain.

Publication status:: Published

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APA Style

Movsisyan, L., Kondratuk, D., Franz, M., Thompson, A., Tykwinski, R., & Anderson, H. (2012). Synthesis of polyyne rotaxanes. Organic Letters, 14(13), 3424–3426.

MLA Style

Movsisyan, L., et al. “Synthesis of Polyyne Rotaxanes.” Organic Letters, vol. 14, no. 13, 2012, pp. 3424–26.

Chicago Style

Movsisyan, L, D Kondratuk, M Franz, A Thompson, R Tykwinski, and H Anderson. 2012. “Synthesis of Polyyne Rotaxanes.” Organic Letters 14 (13): 3424–26.
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Publisher copy:: 10.1021/ol301392t

Authors

+ Movsisyan, L More by this author

Role:: Author

+ Kondratuk, D More by this author

Role:: Author

+ Franz, M More by this author

Role:: Author

+ Thompson, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Tykwinski, R More by this author

Role:: Author

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Journal:: Organic letters More from this journal
Volume:: 14
Issue:: 13
Pages:: 3424-3426
Publication date:: 2012-07-01
DOI:: 10.1021/ol301392t
EISSN:: 1523-7052
ISSN:: 1523-7060

Language:: English
Keywords:: Molecular Structure

Rotaxanes

Models, Molecular

Polyacetylenes
Pubs id:: pubs:339831
UUID:: uuid:ee9a1d9a-9101-481a-a44f-6ee5ac7c7c43
Local pid:: pubs:339831
Source identifiers:: 339831
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2012

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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