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A Halogen-Bonding Bis-Triazolium Rotaxane for Halide-Selective Anion Recognition.

Abstract:

A systematic study on the anion-binding properties of acyclic halogen- and hydrogen-bonding bis-triazolium carbazole receptors is described. The halide-binding potency of halogen-bonding bis-iodotriazolium carbazole receptors was found to be far superior to their hydrogen-bonding bis-triazolium-based analogues. This led to the synthesis of a mixed halogen- and hydrogen-bonding rotaxane host containing a bis-iodotriazolium carbazole axle component. The rotaxane's anion recognition properties, ...

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Publisher copy:
10.1002/chem.201405578

Authors


Mullaney, BR More by this author
Partridge, BE More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication date:
2014-11-05
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:ee7e2423-8cbe-4955-a098-16f0aeac7a84
Source identifiers:
492037
Local pid:
pubs:492037

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