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Millimetre-wave and magnetic studies on a high-spin molecule, Cr-10(OMe)(20)(O2CCMe3)(10)

Abstract:
We report millimetre-wave and magnetic measurements on single crystals of the high-spin molecular magnet, Cr-10(OMe)(20)(O2CCMe3)(10). The susceptibility data obtained using a SQUID magnetometer indicate that this molecule has a total spin of S = 15. The temperature dependence of the magnetisation allows us to estimate the intermolecular exchange constant. The EPR spectra were obtained at different frequencies, angles and temperatures. The results are compared with numerical simulations allowing determination of the Hamiltonian parameters.
Publication status:
Published

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Publisher copy:
10.1051/jp4:2004114155

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author


Journal:
JOURNAL DE PHYSIQUE IV More from this journal
Volume:
114
Pages:
645-647
Publication date:
2004-04-01
Event title:
5th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets (ISCOM2003)
DOI:
EISSN:
1764-7177
ISSN:
1155-4339


Pubs id:
pubs:16924
UUID:
uuid:ee141d70-47dc-4a3f-913d-e8fd3e0edae9
Local pid:
pubs:16924
Source identifiers:
16924
Deposit date:
2012-12-19
ARK identifier:

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