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Journal article

Photocatalytic stannylation of white phosphorus

Abstract:
Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P4) using a cheap, commercially-available distannane, (Bu3Sn)2, and anthraquinone as a simple photocatalyst. Subsequent ‘one pot’ transformation of the resulting stannylated monophosphine intermediate (Bu3Sn)3P provides direct, convenient and versatile access to valuable OPCs such as acylated phosphines and tetraalkylphosphonium salts
Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1039/d2cc03474c
Publication website:
https://epub.uni-regensburg.de/53998/1/d2cc03474c.pdf

Authors

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Role:
Author
ORCID:
0000-0003-4066-6483
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Institution:
University of Oxford
Role:
Author
ORCID:
0000-0001-7826-9833


More from this funder
Funder identifier:
10.13039/100010663
Grant:
CoG 772299
More from this funder
Funder identifier:
10.13039/501100000266
Grant:
EP/V056069/1


Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
58
Issue:
64
Pages:
8986-8989
Publication date:
2022-08-09
DOI:
EISSN:
1364-548X
ISSN:
1359-7345


Language:
English
Keywords:
Pubs id:
1270280
Local pid:
pubs:1270280
Source identifiers:
W4285506254
Deposit date:
2026-04-27
ARK identifier:
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