- Abstract:
-
Reactions of azide ion with 2-O-trifluoromethanesulphonates of both 34:67-di-O-isopropylidene-D-glycero-D-talo-hepton-0-15-lactone and of 34;67-di-O-isopropylidene-D-glycero-D-galacto-heptono-1-5-lactone give predominantly 2-azido-2-deoxy-3 4:6 7-di-O-isopropylidene-D-glycero-D-galacto 5-lactone initially which then isomerises under the reaction conditions to 2-azido-2-deoxy-34:67-di-O-isopropylidene-Dglycerol-D-talo-heptono-1 X-ray crystal structure analyses of 34;67-di-O-isopropylidene-D-gl...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/S0040-4020(01)97581-7
-
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- Journal:
- TETRAHEDRON
- Volume:
- 46
- Issue:
- 1
- Pages:
- 19-32
- Publication date:
- 1990-01-01
- DOI:
- ISSN:
-
0040-4020
- URN:
-
uuid:ee047bcd-4c93-4025-bf82-6788666ab797
- Source identifiers:
-
43320
- Local pid:
- pubs:43320
- Language:
- English
- Copyright date:
- 1990
Journal article
RETENTION AND APPARENT INVERSION DURING AZIDE DISPLACEMENT OF ALPHA-TRIFLATES OF 1,5-LACTONES
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