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ROTATING-DISK ELECTRODE VOLTAMMETRY - THE CATALYTIC MECHANISM (EC) AND ITS NUANCES

Abstract:
The various mechanistic nuances of the catalytic (EC′) mechanism have been considered and it has been shown that steady-state rotating-disc voltammetry alone can discriminate between almost all of the various pathways considered. This deduction has been illustrated with reference to, first, the oxidation of the acetate anion in acetonitrile solution by means of the electrogenerated radical cation of tris(p-bromophenyl)amine and secondly, to the reduction of t-butyl bromide, in the same solvent, mediated through the radical anion of fluoranthene.
Publication status:
Published

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Publisher copy:
10.1039/f19888402013

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I More from this journal
Volume:
84
Issue:
6
Pages:
2013-2025
Publication date:
1988-01-01
DOI:
ISSN:
0300-9599


Language:
English
Pubs id:
pubs:42886
UUID:
uuid:edbd7b35-06fc-4876-8ca9-e3e1426a5522
Local pid:
pubs:42886
Source identifiers:
42886
Deposit date:
2012-12-19
ARK identifier:

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