Journal article

Ammonium directed dihydroxylation of N,N-dibenzylaminocyclohex-2-ene: metal-free syntheses of the diastereoisomers of 3-dibenzylamino-1,2-dihydroxycyclohexane.

Abstract:: Treatment of N,N-dibenzylaminocyclohex-2-ene with mCPBA in the presence of CCl3CO2H gives 1,2-anti-2,3-syn-1-trichloroacetoxy-2-hydroxy-3-N,N-dibenzylaminocyclohexane with high diastereoselectivity; this methodology has been used to facilitate the metal-free stereoselective syntheses of all the diastereoisomers of 3-dibenzylamino-1,2-dihydroxycyclohexane.

Publication status:: Published

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APA Style

Davies, S., Long, M., & Smith, A. (2005). Ammonium directed dihydroxylation of N,N-dibenzylaminocyclohex-2-ene: metal-free syntheses of the diastereoisomers of 3-dibenzylamino-1,2-dihydroxycyclohexane. Chemical Communications, 36, 4536–4538.

MLA Style

Davies, S, et al. “Ammonium Directed Dihydroxylation of N,N-Dibenzylaminocyclohex-2-Ene: Metal-Free Syntheses of the Diastereoisomers of 3-Dibenzylamino-1,2-Dihydroxycyclohexane.” Chemical Communications, no. 36, 2005, pp. 4536–38.

Chicago Style

Davies, S, M Long, and A Smith. 2005. “Ammonium Directed Dihydroxylation of N,N-Dibenzylaminocyclohex-2-Ene: Metal-Free Syntheses of the Diastereoisomers of 3-Dibenzylamino-1,2-Dihydroxycyclohexane.” Chemical Communications, no. 36: 4536–38.
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Publisher copy:: 10.1039/b509088a

Authors

+ Davies, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Long, M More by this author

Role:: Author

+ Smith, A More by this author

Role:: Author

Journal:: Chemical Communications More from this journal
Issue:: 36
Pages:: 4536-4538
Publication date:: 2005-09-01
DOI:: 10.1039/b509088a
EISSN:: 1364-548X
ISSN:: 1359-7345

Language:: English
Pubs id:: pubs:110553
UUID:: uuid:ed79f36d-c1d0-42cf-81cb-e9810db2a2d6
Local pid:: pubs:110553
Source identifiers:: 110553
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_ed79f36dc1d042cf81cbe9810db2a2d6

Terms of use

Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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