Journal article icon

Journal article

Dynamics of the reaction of O(3P) atoms with alkylthiol self-assembled monolayers

Abstract:

We have studied the dynamics of the reactions of O(3P) atoms with alkylthiol self-assembled monolayers (SAMs). Superthermal O(3P) atoms, with a fairly broad distribution of laboratory-frame kinetic energies (mean = 16 kJ mol-1, fwhm = 26 kJ mol-1),were generated by 355 nm photolysis of NO2 introduced at a low pressure above the SAM surface. Nascent OH v' = 0 products were detected by laser-induced fluorescence. SAMs of two different alkyl chain lengths, C6 and C18, were studied. The existence...

Expand abstract

Actions


Access Document


Publisher copy:
10.1021/jp8109868

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Materials
Raisanen, MT More by this author
Costen, ML More by this author
McKendrick, KG More by this author
Journal:
Journal of Physical Chemistry A
Volume:
113
Issue:
16
Pages:
4320-4329
Publication date:
2009-04-23
DOI:
EISSN:
1520-5215
ISSN:
1089-5639
URN:
uuid:ed63039d-768b-422c-919e-b1fd7b015303
Source identifiers:
294896
Local pid:
pubs:294896
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP