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Asymmetric electrophilic fluorocyclization with carbon nucleophiles.

Abstract:
Twist of 'F'ate: Various helical-shaped fluorinated tetracyclic molecules were prepared by fluorocarbocyclization of prochiral alkenes. The development of a new class of chiral Selectfluor (1) proved instrumental in developing an asymmetric variant of this transformation. These novel chiral N-F reagents are readily accessible by fluorine transfer from shelf-stable N-fluoropyridinium salts. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
Publication status:
Published

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Publisher copy:
10.1002/anie.201304845

Authors


Wolstenhulme, JR More by this author
Rosenqvist, J More by this author
Ilupeju, J More by this author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
52
Issue:
37
Pages:
9796-9800
Publication date:
2013-09-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:ed50c753-279c-4d1d-b180-4eb98188855d
Source identifiers:
414479
Local pid:
pubs:414479

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