Journal article
Asymmetric electrophilic fluorocyclization with carbon nucleophiles.
- Abstract:
- Twist of 'F'ate: Various helical-shaped fluorinated tetracyclic molecules were prepared by fluorocarbocyclization of prochiral alkenes. The development of a new class of chiral Selectfluor (1) proved instrumental in developing an asymmetric variant of this transformation. These novel chiral N-F reagents are readily accessible by fluorine transfer from shelf-stable N-fluoropyridinium salts. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/anie.201304845
Authors
- Journal:
- Angewandte Chemie (International ed. in English) More from this journal
- Volume:
- 52
- Issue:
- 37
- Pages:
- 9796-9800
- Publication date:
- 2013-09-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:414479
- UUID:
-
uuid:ed50c753-279c-4d1d-b180-4eb98188855d
- Local pid:
-
pubs:414479
- Source identifiers:
-
414479
- Deposit date:
-
2013-11-17
- ARK identifier:
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- Copyright date:
- 2013
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