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Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis.

Abstract:
(Chemical Equation Presented) The first catalytic route toward the title compounds by asymmetric ring-closing metathesis is described. A remarkable reversal of enantioselectivity is observed when the achiral imido ligand of the chiral molybdenum-catalyst is changed (see scheme), thus highlighting the importance of the achiral and the chiral ligands in catalyst design. © 2009 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200805066

Authors


Harvey, JS More by this author
Malcolmson, SJ More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
48
Issue:
4
Pages:
762-766
Publication date:
2009
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:ed209cfd-176f-4e76-8d5c-59bcd583a6d8
Source identifiers:
34533
Local pid:
pubs:34533

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