Journal article

Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis.

Abstract:: (Chemical Equation Presented) The first catalytic route toward the title compounds by asymmetric ring-closing metathesis is described. A remarkable reversal of enantioselectivity is observed when the achiral imido ligand of the chiral molybdenum-catalyst is changed (see scheme), thus highlighting the importance of the achiral and the chiral ligands in catalyst design. © 2009 Wiley-VCH Verlag GmbH and Co. KGaA.

Publication status:: Published

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APA Style

Harvey, J., Malcolmson, S., Dunne, K., Meek, S., Thompson, A., Schrock, R., Hoveyda, A., & Gouverneur, V. (2009). Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis. Angewandte Chemie (International Ed. in English), 48(4), 762–766.

MLA Style

Harvey, J, et al. “Enantioselective Synthesis of P-Stereogenic Phosphinates and Phosphine Oxides by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis.” Angewandte Chemie (International Ed. in English), vol. 48, no. 4, 2009, pp. 762–66.

Chicago Style

Harvey, J, S Malcolmson, K Dunne, et al. 2009. “Enantioselective Synthesis of P-Stereogenic Phosphinates and Phosphine Oxides by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis.” Angewandte Chemie (International Ed. in English) 48 (4): 762–66.
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Publisher copy:: 10.1002/anie.200805066

Authors

+ Harvey, J More by this author

Role:: Author

+ Malcolmson, S More by this author

Role:: Author

+ Dunne, K More by this author

Role:: Author

+ Meek, S More by this author

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+ Thompson, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

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Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 48
Issue:: 4
Pages:: 762-766
Publication date:: 2009-01-01
DOI:: 10.1002/anie.200805066
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: Phosphines

Oxides

Phosphinic Acids

Stereoisomerism

Catalysis

Molybdenum
Pubs id:: pubs:34533
UUID:: uuid:ed209cfd-176f-4e76-8d5c-59bcd583a6d8
Local pid:: pubs:34533
Source identifiers:: 34533
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_ed209cfd176f4e768d5c59bcd583a6d8

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Copyright date:: 2009

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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