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NIOBIUM METALLABORANES - A NOVEL METALLABORANE ANALOG OF PENTABORANE(11)

Abstract:
Treatment of [Nb(η-C5H5)2H3] with pentaborane(9) gives the novel arachno-metallaboranes [Nb(η-C5H5)2B4H9 ] (1) and [Nb(η-C5H5)2B3H8 ] (2). Compound 1 is the first reported base subrogated analogue of the neutral arachno-pentaborane(11) and has an apex to niobium hydrogen bridge. Compound 2, for which the X-ray crystal structure has been determined, is an analogue of the neutral arachno-tetraborane(10). © 1990.
Publication status:
Published

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Publisher copy:
10.1016/0022-328X(90)85235-Q

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY More from this journal
Volume:
382
Issue:
1-2
Pages:
C1-C5
Publication date:
1990-02-06
DOI:
ISSN:
0022-328X


Language:
English
Pubs id:
pubs:51393
UUID:
uuid:ecc1a5b7-4041-4f6f-815b-e98dc0f9f20d
Local pid:
pubs:51393
Source identifiers:
51393
Deposit date:
2012-12-19
ARK identifier:

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