Journal article
NIOBIUM METALLABORANES - A NOVEL METALLABORANE ANALOG OF PENTABORANE(11)
- Abstract:
- Treatment of [Nb(η-C5H5)2H3] with pentaborane(9) gives the novel arachno-metallaboranes [Nb(η-C5H5)2B4H9 ] (1) and [Nb(η-C5H5)2B3H8 ] (2). Compound 1 is the first reported base subrogated analogue of the neutral arachno-pentaborane(11) and has an apex to niobium hydrogen bridge. Compound 2, for which the X-ray crystal structure has been determined, is an analogue of the neutral arachno-tetraborane(10). © 1990.
- Publication status:
- Published
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- Publisher copy:
- 10.1016/0022-328X(90)85235-Q
Authors
- Journal:
- JOURNAL OF ORGANOMETALLIC CHEMISTRY More from this journal
- Volume:
- 382
- Issue:
- 1-2
- Pages:
- C1-C5
- Publication date:
- 1990-02-06
- DOI:
- ISSN:
-
0022-328X
- Language:
-
English
- Pubs id:
-
pubs:51393
- UUID:
-
uuid:ecc1a5b7-4041-4f6f-815b-e98dc0f9f20d
- Local pid:
-
pubs:51393
- Source identifiers:
-
51393
- Deposit date:
-
2012-12-19
- ARK identifier:
Terms of use
- Copyright date:
- 1990
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