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Controlling structure and reactivity in cationic Solid–State Molecular OrganoMetallic (SMOM) systems using anion templating

Abstract:

The role that the supporting anion has on the stability, structure and catalytic performance, in Solid-state Molecular Organ-oMetallic systems (SMOM) based upon [Rh(Cy2PCH2CH2PCy2)(η2η2-NBD)][BArX4], [1-NBD][BArX4], is reported (X = Cl, F, H; NBD = norbornadiene). The tetra–aryl borate anion is systematically varied at the 3,5–position, ArX= 3,5-X2C6H3, and the stability and structure in the solid–state compared with the previously reported [1-NBD][BArCF34] complex. Single crystal X-ray cryst...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/acs.organomet.8b00215

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
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Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Volume:
37
Issue:
20
Pages:
3524–3532
Publication date:
2018-06-04
Acceptance date:
2018-05-21
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Pubs id:
pubs:853089
URN:
uri:ec817a84-5da1-46f0-95b8-20d9257ff913
UUID:
uuid:ec817a84-5da1-46f0-95b8-20d9257ff913
Local pid:
pubs:853089

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