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Fast scan linear sweep voltammetry at a high-speed wall-tube electrode

Abstract:

The application of fast-scan linear sweep voltammetry methods to a high-speed wall-tube electrode (HWTE) is reported. Experiments are reported for the oxidation of N,N,N′,N′-tetramethyl-p-phenylenediamine (TMPD) in propylene carbonate solution containing 0.10 M tetrabutylammonium perchlorate for a 24 μm radius platinum microdisk electrode housed within the HWTE using a range of scan rates from 200 to 3000 V s-1 and average flow jet velocities from 0.24 to 9.4 m s-1 (corresponding to volume fl...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
557
Pages:
99-107
Publication date:
2003-10-15
DOI:
ISSN:
0022-0728
URN:
uuid:ec243b5b-043a-4114-b939-fc57c0129abd
Source identifiers:
38816
Local pid:
pubs:38816

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