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(C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topology

Abstract:
The title compound, poly[N,N,N′N′-tetramethylpropane-1,3-diaminium [aquatetraoxotri-μ3-sulfatodiuranate(VI)]], (C7H 20N2)[(UO2)2(SO4) 3(H2O)]n, contains two-dimensional [(UO 2)2(SO4)3(H20)] 2~ layers that are unprecedented in uranium chemistry. The layers in this compound are separated by C7H20N22+ cations, forming the basis of an extensive hydrogen-bonding network. An independent intralayer hydrogen-bonding network is also observed, involving water molecules bound directly to a uranium centre. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
Publication status:
Published

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Publisher copy:
10.1107/S1600536805009670

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE More from this journal
Volume:
61
Issue:
5
Pages:
M807-M810
Publication date:
2005-05-01
DOI:
EISSN:
1600-5368
ISSN:
1600-5368


Language:
English
Pubs id:
pubs:51163
UUID:
uuid:ebe9ccb5-68b2-441e-9af8-c859f6b24785
Local pid:
pubs:51163
Source identifiers:
51163
Deposit date:
2012-12-19
ARK identifier:

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