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Sodium, magnesium and zinc complexes of mono(phenolate) heteroscorpionate ligands

Abstract:

The reaction of bis(3,5-dimethylpryrazolyl)methylphenol N₂OArH (1) with NaH in THF formed dimeric [Na(κ²-N₂OAr)(THF)]₂ (2), which contains a κ²(N,O)-bound bidentate N₂OAr)ligand. The reactopm of 1 with MgⁿBu₂ gave the four-coordinate monomeric butyl compound Mg(N₂OAr)ⁿBu (3), whereas with ⁿBuMgCl, a mixture of products was formed, including the six-coordinate homoleptic species Mg(N₂OAr)₂ (4). The reaction of [Na(κ²-N₂OAr)(THF)...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/b813116c

Authors


More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemistry Research Laboratory
Engineering and Physical Sciences Research Council More from this funder
Oxford University's Clarendon Fund More from this funder
European Union More from this funder
Publisher:
Royal Society of Chemistry Publishing Publisher's website
Journal:
Dalton Transactions Journal website
Issue:
1
Pages:
85-96
Publication date:
2009
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:ebe48ce6-5650-4dcc-89b2-ac58da9bb0e1
Local pid:
ora:4488
Language:
English
Subjects:

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