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Crystallization and phase separation in nonadditive binary hard-sphere mixtures

Abstract:
We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well.
Publication status:
Published

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Publisher copy:
10.1103/physreve.61.r1028

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Theoretical Physics
Hansen, JP More by this author
Journal:
Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics
Volume:
61
Issue:
2
Pages:
R1028-R1031
Publication date:
2000-02-05
DOI:
EISSN:
1095-3787
ISSN:
1063-651X
URN:
uuid:ebb82d93-141a-4ed1-91c2-4a8e55b915e4
Source identifiers:
153994
Local pid:
pubs:153994
Language:
English

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