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High performance PbS quantum dot/graphene hybrid solar cell with efficient charge extraction

Abstract:
Hybrid colloidal quantum dot (CQD) solar cells are fabricated from multilayer stacks of lead sulfide (PbS) CQD and single layer graphene (SG). The inclusion of graphene interlayers is shown to increase power conversion efficiency by 9.18%. It is shown that the inclusion of conductive graphene enhances charge extraction in devices. Photoluminescence shows that graphene quenches emission from the quantum dot suggesting spontaneous charge transfer to graphene. CQD photodetectors exhibit increased photoresponse and improved transport properties. We propose that the CQD/SG hybrid structure is a route to make CQD thin films with improved charge extraction, therefore resulting in improved solar cell efficiency.
Publication status:
In press
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acsami.6b02544

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author


Publisher:
American Chemical Society
Journal:
ACS Applied Materials and Interfaces More from this journal
Volume:
8
Issue:
22
Pages:
13902–13908
Publication date:
2016-05-23
Acceptance date:
2016-05-13
DOI:
ISSN:
1944-8244


Keywords:
Pubs id:
pubs:622968
UUID:
uuid:eba67809-549a-421a-86dd-8be32826ebc6
Local pid:
pubs:622968
Source identifiers:
622968
Deposit date:
2016-05-19
ARK identifier:

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