- Abstract:
-
We report here a structural and photophysical study of lanthanide complexes with the di-deprotonated form of the bibracchial lariat ether N,N'-bis(2-salicylaldiminobenzyl)-4,10-diaza-12-crown-4 (L(3)) (Ln = Ho(III)-Lu(III)). The X-ray crystal structures of [Ho(L(3)-2H)](ClO(4)) (1) and [Er(L(3)()-2H)](ClO(4)) (2) show the metal ion being eight-coordinate and deeply buried in the cavity of the dianionic receptor. Both sidearms of L(3) are on the same side of the crown moiety, resulting in a sy...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic048172a
-
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- Journal:
- Inorganic chemistry
- Volume:
- 44
- Issue:
- 12
- Pages:
- 4254-4262
- Publication date:
- 2005-06-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:eb9d43a4-347d-4265-99df-2264bceebfb0
- Source identifiers:
-
46796
- Local pid:
- pubs:46796
- Language:
- English
- Copyright date:
- 2005
Journal article
Structural and photophysical properties of lathanide(III) complexes with a novel octadentate iminophenolate bibracchial lariat ether.
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