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Structural and photophysical properties of lathanide(III) complexes with a novel octadentate iminophenolate bibracchial lariat ether.

Abstract:

We report here a structural and photophysical study of lanthanide complexes with the di-deprotonated form of the bibracchial lariat ether N,N'-bis(2-salicylaldiminobenzyl)-4,10-diaza-12-crown-4 (L(3)) (Ln = Ho(III)-Lu(III)). The X-ray crystal structures of [Ho(L(3)-2H)](ClO(4)) (1) and [Er(L(3)()-2H)](ClO(4)) (2) show the metal ion being eight-coordinate and deeply buried in the cavity of the dianionic receptor. Both sidearms of L(3) are on the same side of the crown moiety, resulting in a sy...

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Publication status:
Published

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Publisher copy:
10.1021/ic048172a

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Inorganic chemistry
Volume:
44
Issue:
12
Pages:
4254-4262
Publication date:
2005-06-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:eb9d43a4-347d-4265-99df-2264bceebfb0
Source identifiers:
46796
Local pid:
pubs:46796
Language:
English

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