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Fluorodesilylation of alkenyltrimethylsilanes: a new route to fluoroalkenes and difluoromethyl-substituted amides, alcohols or ethers

Abstract:
A range of alkenyltrimethylsilanes are converted to alkenyl fluorides by reaction with one equivalent of Selectfluor™ (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)), or difluoromethyl-substituted alcohols, ethers or amides using an excess of Selectfluor™ in the presence of various nucleophiles.
Publication status:
Published

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Publisher copy:
10.1039/b009179k

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
CHEMICAL COMMUNICATIONS
Issue:
03
Pages:
233-234
Publication date:
2001
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:ea87e65a-9585-43f0-b03b-2b47c2698142
Source identifiers:
37745
Local pid:
pubs:37745
Language:
English

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