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Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes

Abstract:

Novel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N′-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1′-bis(benzylaminomethyl)ferrocene (8) and 1,1′-bis((ferrocenylmethyl)aminomethyl)ferrocene (9) with carbon disulfide, potassium hydroxide and transition metal (zinc, copper, nickel) acetate in high yields (52-82%) and characterised...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
637
Pages:
89-93
Publication date:
2001-12-03
DOI:
ISSN:
0022-328X
URN:
uuid:ea54b854-8aa7-4969-9655-8e0f8c02e66c
Source identifiers:
38039
Local pid:
pubs:38039

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